Alkenyl succinic anhydride.

The use of a combination of calcium carbonate (CaCO3) and alkenyl-succinic-anhydride (ASA)-modified microfibrillated cellulose (AMFC) as a filler for high-density polyethylene (HDPE) has been investigated. AMFC and CaCO3 were mixed with HDPE using a twin-screw extruder, and the resulting composites were injection molded. …Cationic starch and polyacrylamides for alkenyl succinic anhydride (ASA) emulsification for sizing of cellulosic fibers. Paper is composed of polysaccharides mainly cellulose and carbohydrates. The hydroxyl groups present in cellulose react with various substances added to fibrous slurry. Treating the cellulosic fibers…. Succinic anhydride. Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). ?) Succinic anhydride, is an organic compound with the molecular formula (CH 2 CO) 2 O. This colorless solid is the acid anhydride of succinic acid . Alkenyl succinic anhydride (ASA) is one of the most prominent paper sizing agents worldwide. Commercial products start from isomerized C16-18 olefins with certain distribution of the double bond along the alkyl chain. This distribution is then found again in the product ASA which renders mechanistic studies on ASA binding to the cellulose …

Succinic anhydride appears as colorless needles or white crystalline solid. Melting point 237 °F. Sublimes at 239 °F at 5 mmHg pressure; and at 198 °F and 1 mmHg pressure. Moderately toxic and an irritant. CAMEO Chemicals. Succinic anhydride is a cyclic dicarboxylic anhydride and a tetrahydrofurandione.Sep 3, 2021 · Press release, September 3rd 2021 at 08:00 EEST

In this work, we modified this water-soluble polymer with alkenyl succinic anhydride in order to attach a hydrophobic group to it. The modification used two reagents: octenyl succinic anhydride and tetrapropenyl succinic anhydride. Reactions were conducted at 120 °C using dimethyl sulfoxide as a solvent, with conversions better than 88%.

Abstract. Alkenyl Succinic Anhydride (ASA) is a sizing agent used in papermaking to increase the water repellency of paper. Almost 60 years after the …It is well known that alkenyl succinic anhydride (ASA), an alkaline sizing agent, when applied to cellulosic fibers will impart a resistance to the absorption of …Alkenyl Succinic Anhydride (ASA) is a sizing agent used in papermaking to increase the water repellency of paper. Almost 60 years after the introduction of the chemical in papermaking, scientists still have differing views on how ASA interacts with cellulose.Alkenyl succinic anhydride from methyl oleate was isolated by column chromatography and analyzed by IR, 1 Hand 13 C-NMR and MS. The optimal reaction conditions for obtaining the maximum yield of alkenyl succinic anhydride from methyl oleate in the experimental domain (80%) were 210-220 °C and a maleic …In this work, we modified this water-soluble polymer with alkenyl succinic anhydride in order to attach a hydrophobic group to it. The modification used two reagents: octenyl succinic anhydride and tetrapropenyl succinic anhydride. Reactions were conducted at 120 °C using dimethyl sulfoxide as a solvent, with conversions better than …

In this work, we modified this water-soluble polymer with alkenyl succinic anhydride in order to attach a hydrophobic group to it. The modification used two reagents: octenyl succinic anhydride and tetrapropenyl succinic anhydride. Reactions were conducted at 120 °C using dimethyl sulfoxide as a solvent, with conversions better than 88%.

alkenyl succinic anhydride; emulsion; stability; Acknowledgements. The authors are grateful for the financial provided by the National Natural Science Foundation of China (52172147), the Natural Science Foundation of Shandong Province (ZR2022MB095), Shandong Province Key Research and Development Program (2021ZDSYS18), and the …

The Money Channel contains articles that answer all of your financial questions. Check out the HowStuffWorks Business and Money Channel. Topics to Explore: Advertisement Advertisem...Among them, alkenyl succinic anhydride (ASA) is a commonly applied neutral sizing agent, and needs to be prepared as an oil-in-water emulsion before sizing (Guodong Li et al. 2017; Yu et al. 2020).The alkenyl succinic anhydrides are valuable precursors for the preparation of alkyl succinic anhydrides. ABSTRACT A process for producing alkenyl succinic anhydrides by the reaction of an olefin with maleic anhydride in …Succinic anhydride can be considered a promising modifying agent for nanocellulose since it enables the introduction of aliphatic chains along with carboxylic …In the present work, surface modification of CNFs with alkenyl succinic anhydride (ASA) was studied to improve the mechanical properties of CNF-reinforced HDPE. ASA-modified polysaccharides such as waxy maize starch nanocrystals [18], chitin whiskers [19], cellulose whiskers [20], or CNC [21] have been studied during the past few decades. Yuan ...Apr 14, 2023 ... Fenbufen Part 2/3. Here's a quick preparation video. The dehydration of succinic acid to succinic anhydride using acetic anhydride following ...By voting to confirm Kavanaugh, Republicans are making a "huge mistake," women's activists say. With a vote of 50-48-1, the US Senate confirmed Brett Kavanaugh to the Supreme Court...

No reproductive effects were observed in parental reproductive organs or performance after exposure to tripropenyl succinic anhydride, a member of the C8 -C12 alkenyl succinic anhydride category. The general NOAEL was 50 mg/kg bw/d for body weight effects; the NOAEL for reproductive effects could be higher.A 48-hour mutiny could undo years of progress. From the fancy French-style cafes to the fancy malls of capital city Abidjan, Côte d’Ivoire has been a picture of economic stability ...Alkenyl succinic anhydrides and olefin-maleic anhydride copolymers were synthesized from straight and branched olefins which were reacted with alcohols and.Vertellus (Indianapolis, Ind.; www.vertellus.com) announced today it has acquired Bercen Chemicals, a leading U.S. supplier of alkyl succinic anhydrides and additives used in the fuel, lubricant, and paper industries. “This acquisition expands the range of products Vertellus is able to offer to the North American market” said Jim Elliott, …Succinic Anhydride. 113 Alkenyl succinic anhydrides (extensively used in the papermaking industry as paper sizing agents when manufactured by reaction of maleic anhydride with C14–C22 i-olefins) have been prepared by the ene reaction of the methyl esters of high-oleic sunflower oil with maleic anhydride in a 50% xylene medium.Jun 1, 2017 · Stabilizing alkenyl succinic anhydride (ASA) emulsions using fine particles instead of cationic starch have attracted much attention in recent years. Herein, starch nanocrystals (SNCs) made from maize starch by H 2 SO 4 hydrolysis were used to co-stabilize ASA emulsions with fluorescent carbon dots (CDs) made hydrothermally from gelatin.

Alkenyl succinic anhydride (ASA) is widely used in papermaking industry as an internal sizing agent. In situ emulsification of ASA using cationic starch is conventionally practiced because of the ...

Temperature (K) A B C Reference Comment; 365. - 534. 3.65221: 1433.874-144.107: Stull, 1947: Coefficents calculated by NIST from author's data.Press release, September 3rd 2021 at 08:00 EESTThe URL has moved hereABSTRACT: Alkenyl succinic anhydrides (ASA) were prepared by an -ene reaction of n-alkyl (C1 to C5) oleates with maleic an-hydride. The purified compounds were characterized by FTIR, 1H NMR, and MS analytical methods to elucidate their struc-tures.Vertellus (Indianapolis, Ind.; www.vertellus.com) announced today it has acquired Bercen Chemicals, a leading U.S. supplier of alkyl succinic anhydrides and additives used in the fuel, lubricant, and paper industries. “This acquisition expands the range of products Vertellus is able to offer to the North American market” said Jim Elliott, …In this work, we modified this water-soluble polymer with alkenyl succinic anhydride in order to attach a hydrophobic group to it. The modification used two reagents: octenyl succinic anhydride and tetrapropenyl succinic anhydride. Reactions were conducted at 120 °C using dimethyl sulfoxide as a solvent, with conversions better than 88%.Mar 14, 2022 · Among them, alkenyl succinic anhydride (ASA) is a commonly applied neutral sizing agent, and needs to be prepared as an oil-in-water emulsion before sizing (Guodong Li et al. 2017; Yu et al. 2020). In the traditional emulsifying process, the excessive use of surfactants can facilitate emulsification, but that will have an adverse effect on ... Product name : Succinic anhydride Product Number : 239690 Brand : Aldrich Index-No. : 607-103-00-5 CAS-No. : 108-30-5 1.2 Relevant identified uses of the substance or mixture and uses advised against Identified uses : Laboratory chemicals, Synthesis of substances Uses advised against : The product is being supplied under the TSCA R&D Exemption ...Among them, alkenyl succinic anhydride (ASA) is a commonly applied neutral sizing agent, and needs to be prepared as an oil-in-water emulsion before sizing (Guodong Li et al. 2017; Yu et al. 2020). In the traditional emulsifying process, the excessive use of surfactants can facilitate emulsification, but that will have an adverse effect on ...

Jan 26, 2005 · Alkenyl succinic anhydrides (ASA) have been prepared by ene-reaction of high-oleic sunflower oil methyl esters with maleic anhydride in a 50% xylene medium. Response surface methodology (RSM) was used to investigate the influence of two factors: reaction temperature and molar ratio between maleic anhydride (MA) and methyl esters (SME).

Features. · Alkenyl succinic anhydride having an alkenyl group having 15 carbon atoms. · The resins cured with this product has excellent electrical properties and flexibility. · This product is also easy to handle because it has low viscosity and long pot life (usable period). · Curing agents for epoxy resins.Quantity Value Units Method Reference Comment; Δ r H°-46.86 ± 0.08: kJ/mol: Cm: Conn, Kistiakowsky, et al., 1942: liquid phase; Heat of hydrolysis at 303 KAbstract. Medium and long chain esters of inulin have been prepared by reaction of alkenyl succinic anhydrides (ASA) such as 2-octen-1-ylsuccinic anhydride (OSA), and 2-dodecen-1-ylsuccinic anhydride (DDSA) in aqueous media and aqueous surfactant media, respectively. The design of the chemical process was based on the … 2 -Dodecenyl succinic anhydride is classified as a severe skin irritant, Category 2, according to Regulation EC No. 1272/2008. The substance is classified as an eye irritant, Category 2, by "reading-across" from tetrapropenyl succinic anhydride, a member of the C8 -12 Alkenyl Succinic Anhydride category. Abstract Alkenyl succinic anhydride (ASA) is widely used in papermaking industry as an internal sizing agent. In situ emulsication of ASA using cati-onic starch is conventionally practiced because of the low shelf life of ASA emulsion. We synthesized Janus particles by surfactant-free seeded polymerization to stabilize ASA emulsion.Alkenyl succinic anhydride (ASA) is commonly used in the neutral/alkaline papermaking process. It is an oily monomer and is added to pulp stock in a form of aqueous emulsion at room temperature. It provides on machine sizing because of its high degree of reactivity with the hydroxyl groups on polysaccharide components in the paper substrate [1]. Alkenyl succinic anhydride (ASA for short) is a basic raw material widely used in light industry and fine chemical industry, is widely applied to lubricating oil, waterproof agent, hardener, drying agent and preservative, is particularly applied to the field of papermaking production by using a reactive sizing agent, has the capability of fast reaction with cellulose, and can greatly improve ... Alkenyl succinic anhydride (ASA) is a viscous polar oil, typically used as a paper sizing agent after being emulsified. ASA and water emulsions stabilized by TiO 2 nanoparticles were prepared by adding the aqueous phase to the oil phase. Catastrophic phase inversion from w/o to o/w or w/o/w has been investigated by monitoring the variation of ...Alkenyl succinic anhydrides (ASA) are widely used in the paper industry as paper sizing agents [1, 2]. Other common applications include: wood preservation agents [3], additives for lubricants [4], and monomers for the fabrication ofther­ mosets as the anhydride moiety can react with diamines, diols,Preparation of aryl and alkenyl succinic anhydride hemiesters of hyaluronan2.2.1. Preparation of low molecular weight (LMW) hyaluronan derivatives. LMW HA (4000, 14,000, 23,000, 30,000 or 100,000 g/mol, 2.50 g, 12.5 mmol HA-monomer) was dissolved overnight at room temperature in deionized water (50 mL) before adjusting pH to 8.5. Succinic anhydride. Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). ?) Succinic anhydride, is an organic compound with the molecular formula (CH 2 CO) 2 O. This colorless solid is the acid anhydride of succinic acid .

Hydrophobically modified inulin from alkenyl succinic anhydride in aqueous media @article{Morros2011HydrophobicallyMI, title={Hydrophobically modified inulin from alkenyl succinic anhydride in aqueous media}, author={Jordi Morros and Bart Levecke and Mar{\'i}a Rosa Infante}, journal={Carbohydrate Polymers}, year={2011}, volume= {84 ...Alkenyl succinic anhydrides (ASA) are derivatives of succinic anhydrides. One H of the succinic anhydride ring is replaced with an iso- alkenyl chain (C 14 to C 22 ). ASA's are colorless and usually viscous liquids. 2 -Dodecenyl succinic anhydride is classified as a severe skin irritant, Category 2, according to Regulation EC No. 1272/2008. The substance is classified as an eye irritant, Category 2, by "reading-across" from tetrapropenyl succinic anhydride, a member of the C8 -12 Alkenyl Succinic Anhydride category. Films obtained from pristine tree gums are often brittle, hygroscopic, and lack mechanical strength. This study focuses on the chemical modification of gum kondagogu using long-chain alkenyl groups of dodecenyl succinic anhydride (DDSA), an esterifying agent that introduces a 12-carbon hydrophobic chain to the kondagogu structure.Instagram:https://instagram. buelos varatosverizon track my phoneel paso to houston txairline ticket to fairbanks Abstract. Alkenyl succinic anhydrides having a decreased amount of tar and color bodies are made by the reaction of an olefin with maleic anhydride in the presence of a tri-orthoalkylphenyl phosphite and optionally a hindered phenolic antioxidant such as 2,4,6-tri- (3,5-di-tert-butyl-4-hydroxybenzyl) mesitylene. jax to miami flightsboston ma to new york ny It is well known that alkenyl succinic anhydride (ASA), an alkaline sizing agent, when applied to cellulosic fibers will impart a resistance to the absorption of water. High reactivity of ASA to cellulosic fiber compared to that of alkyl ketene dimer (AKD) is the main advantage of ASA sizing. Succinic anhydride. Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). ?) Succinic anhydride, is an organic compound with the molecular formula (CH 2 CO) 2 O. This colorless solid is the acid anhydride of succinic acid . discount coupons for michaels Alkenyl succinic anhydride (ASA) was added to the agents that would increase the resistance of cellulose fibers to the adsorption of water under neutral/alkaline conditions (at pH's in the range ...Alkenyl succinic anhydride (ASA) was added to the agents that would increase the resistance of cellulose fibers to the adsorption of water under neutral/alkaline conditions (at pH's in the range of 7.5-8.5) in the 1960's by 0. Wurzburg and E. Mazzerella of the National Starch and Chemical Company [1]. The sodium salt of ASA can be complexed with alum …Alkenyl succinic anhydride, a dicarboxylic anhydride, can be synthesized by the reaction between olefins (C n H 2n) and maleic acid. This compound has two active carboxyl groups from maleic acid which can occur esterification reaction with the hydroxyl groups of polysaccharide.